A Importncia de Monitorar e Controlar as Concentraes e Quantidades das Cargas de DBO5 e DQO em uma Estao de Tratamento de Efluentes de Lodo Ativado - Parte 2IntroduoNeste trabalho pretende-se apresentar algumas ideias para que o leitor possa obter um melhor entendimento do que so e como podem ser monitoradas e controladas as cargas poluidoras orgnicas. Essas cargas so normalmente definidas a partir das medies da Demanda de Oxignio Qumica (DQO) e da Demanda de Oxignio Biolgica (DB05).Nesta parte, so tratados assuntos referentes ao monitoramento e controle das cargas poluidoras orgnicas em uma estao de tratamento de efluentes, como indicado abaixo:1. Qual a faixa ideal de controle das cargas de DQO e DBO5 encontradas na entrada e na sada da fase de tratamento biolgico?2. Quais so os problemas e dificuldades no controle das cargas encontradas em um tanque de aerao?3. Como se podem controlar as cargas excessivas de DQO e DBO5?1. Qual a faixa ideal de controle das cargas de DQO e DBO5 encontradas na entrada e na sada da fase de tratamento biolgico?1.1. Para determinar uma faixa ideal no controle das cargas de DQO e DBO5, primeiramente necessrio comparar os valores das cargas obtidas em uma estao de tratamento de efluentes em operao, com os valores utilizados no projeto de construo da mesma estao. Na tabela n 1 a seguir, so apresentados os valores normais (e no com vazes de pico, que podem ser de 10 15% maiores) utilizados no projeto da mesma estao, com os valores operacionais e que se encontram resumidos na tabela N 1 do trabalho: A Importncia de Monitorar e Controlar as Concentraes e Quantidades das Cargas de DBO5 e DQO em uma Estao de Tratamento de Efluentes de Lodo Ativado Parte 1.

1.2. Como se observa na tabela 1 acima, os dados das cargas utilizados no desenvolvimento de um projeto de uma estao de tratamento de efluente podem ser comparados com os valores operacionais da mesma estao. Esses dados operacionais podem ser consolidados com base em vrios perodos de tempo, conforme demandas do estudo. Na tabela N 2 a seguir, encontram-se lado ao lado os resultados mdios operacionais calculados ao longo de um ano e os respectivos valores do projeto original.

preciso ressaltar que quanto menor for o valor da carga de DBO5 efetivamente lanada nos rios, melhor ser para o meio ambiente. Olhando para o valor encontrado no canto inferior direto da tabela acima, observa-se que a carga de DBO5 efetivamente lanada no meio ambiente, menor que o valor do projeto. Ento, pode-se deduzir, que a ETE est funcionando bem, em relao a remoo de cargas de DBO5, ou seja ela est removendo suficientemente a carga de poluio que est entrando na estao de tratamento de efluente. 1.3. Quais so as faixas ideais de controle das cargas de DQO e DBO5? Entende-se que existem pelo menos duas maneiras de avaliar as variaes nessas cargas e determinar as faixas teis e operacionais para o controle das mesmas entrando em uma ETE. Na tabela N 3 a seguir, levantou-se os valores mdios, mximos, mnimos e o desvio padro de duas cargas poluidoras, entrando no tratamento primrio da ETE, ao longo de um ano. Tambm, incluram-se linhas indicando as cargas nas entradas utilizadas pelo projeto da mesma ETE, e ainda valores similares, mas que so 50 % maiores. Os ltimos valores (50 % maiores e que so chamados valores de picos) foram estimados com base nas faixas utilizadas no projeto, que previa variaes dos valores de F/M considerados aceitveis, em relao a todo o volume do tanque de aerao.

Para o efluente [A] efluente bruto sem slidos, a carga mxima da DQO encontrada, ou seja, 128.398 kg DQO/dia, no superou o valor do projeto de mais 50%, que foi calculada em 210.150 kg DQO/dia. Para os valores da carga de DBO5 do efluente [A], encontrou-se uma situao diferente, pois a carga mxima da DBO5, 80.283 kg DBO5/dia, superou significativamente o valor de pico do projeto, ou seja, que foi calculada em 65.400 kg DBO5/dia.Para o efluente [B] efluente bruto com slidos, os valores mximos, tanto da carga de DQO quanto a carga de DBO5, superaram em muito os respectivos valores de pico do projeto.Outra maneira de avaliar as variaes das cargas na entrada da ETE de comparar o tamanho do valor mdio da uma carga, em porcentagem, com o valor do desvio padro da mesma sequncia de valores. Por exemplo, podem-se utilizar os valores da carga de DQO na entrada do efluente sem slidos ao longo de um ano. Quanto maior for o desvio padro das cargas na entrada da ETE, maior a variao das mesmas cargas em volta do valor mdio. Na tabela N 4 a seguir, pode-se observar variaes de 34% a 74% nos desvios padro e nos valores mdios das diversas cargas poluidoras.

Apesar de o lanamento de uma carga de DBO5 no meio ambiente encontrar-se abaixo do valor projeto, pode se concluir que as grandes variaes das cargas de DQO e DBO5 na entrada da ETE, tornam a operao diria de uma ETE muito difcil, particularmente impedem que ela se torne estvel e funcione de forma eficiente.2. Quais so os problemas e dificuldades no controle das cargas encontradas em um tanque de aerao?2.1. Como o excesso da carga pode criar problemas? Em um tanque de aerao, o volume fixo, portanto, limitada a carga hidrulica do tanque de aerao. Em decorrncia deste fato, tambm o tempo de residncia e de depurao das cargas poluidoras so limitados. Quando uma carga poluidora entrar em um tanque de aerao muito maior do que os limites definidos pelo projeto, no haver tempo suficiente para que ela possa ser removida. Ainda muito importante destacar que existe outro aspecto similar, a questo apresentada acima que diz respeito limitao no volume do tanque de aerao. No desenvolvimento e implantao de um projeto, a quantidade de ar disponvel para misturar e agir com o efluente e com a carga poluente, tambm limitado a um valor mximo. Portanto, a quantidade de oxignio disponvel para depurao das cargas, tambm limitada. Nas situaes onde ocorrem excessos de cargas poluidoras entrando no tanque de aerao, observa-se que alm da massa biolgica no ter tempo suficiente de depurar as cargas, tambm faltar oxignio.Essas condies limitantes permitem que se desenvolvam tipos de bactrias anormais e que vo alterar a qualidade fsica da biomassa, ou do lodo. Mesmo que as variaes das cargas em excesso sejam de curta e transitria durao, elas dificultam manter a quantidade da carga final em um nvel aceitvel. Nessa situao podem ocorrer alteraes na qualidade da biomassa que criariam srias dificuldades no controle de slidos dentro da fase de tratamento biolgico da ETE, e at na quantidade de slidos suspensos no efluente tratado.2.2. Como uma carga de poluentes insuficiente pode criar problemas na operao de uma ETE? Os casos onde ocorre uma falta de carga de DQO ou DBO5 no so muito frequentes, e em geral so mais fceis de resolver. Mas os problemas que podem surgir so similares situao de um excesso da carga, mas no sentido inverso. Nas situaes onde a carga de poluente e a carga hidrulica so insuficientes, o tempo de depurao ser mais longo do que o estipulado no projeto, e a biomassa ou lodo vai ficar em contato excessivo com o ar e o oxignio. Os resultados destas condies tambm podem criar problemas na qualidade da biomassa e no controle de slidos dentro da ETE. Dentro destes problemas em geral, destaca-se o fenmeno chamado pin floc, onde os flocos de lodo ficam pequenos e quebrados.3. Como se podem controlar as cargas excessivas de DQO e DBO5?3.1. O controle das cargas de DQO e DBO5 na entrada da ETE ao mesmo tempo uma operao muito importante no controle dirio de uma ETE, e tambm das mais difceis a ser executada. O operador da ETE normalmente tem pouca possibilidade de modificar a quantidade e a qualidade do efluente bruto que enviado ETE. Quando ele toma conhecimento sobre modificaes significantes relacionadas a qualidade e quantidade de efluente, muitas vezes tarde demais para efetivar o controle necessrio. O excesso da carga hidrulica e poluente j poder estar dentro da fase de tratamento primrio ou secundrio da ETE.Um operador tem duas formas bsicas de tentar controlar e limitar que um excesso da carga como DQO e DBO5 entre na estao de tratamento. A primeira dela diz respeito ateno e ao acompanhamento constante das condies operacionais das reas produtivas da planta. A segunda forma diz respeito ao uso adequado das lagoas de emergncia. Talvez seja possvel acrescentar uma terceira opo, que seria a integrao das duas formas apontadas acima. Observa-se que na primeira forma de controle, um operador dever acompanhar os nveis dos diversos tanques dos licores e guas existentes nas diversas reas produtivas. Nesta forma de controle devero ser monitorados, tambm os diversos parmetros de qualidade dos efluentes setoriais. Essas informaes devero ser disponibilizadas on-line, como se destaca a seguir: pH, condutividade e a prpria vazo dos efluentes setoriais. A ateno do operador dever ser redobrada durante as paradas eventuais da fbrica, sejam elas emergenciais ou planejadas. Uma estreita interao dos operadores com os supervisores e os responsveis pelas reas produtivas podem contribuir bastante para o controle da carga poluidora enviada a ETE. Esse controle deve ocorrer por meio do acompanhamento de picos, dentro de um turno especfico de operao e de forma diria. Tambm, contribui muito para um melhor controle das cargas poluidoras por parte dos operadores da ETE, o entendimento e o acompanhamento dos procedimentos operacionais padronizados pelas reas produtivas, como a respeito dos programas ISO 14.001 e ISO 9.000. O desvio do efluente bruto para um ou mais lagoas de emergncia outra forma que um operador pode utilizar para controlar e limitar a entrada excessiva de cargas de DQO e DBO5 na ETE. Neste caso, no dispensvel a necessidade do operador se envolver e interagir com os supervisores das reas produtivas. O uso do volume livre das lagoas no pode ser aplicado em uma forma continua, pois, pode-se chegar a um momento em que a lagoa ou lagoas ficaro cheias. No momento do desvio do efluente para a lagoa de emergncia, necessrio que se estabelea um plano de retorno do efluente para a ETE, onde ele ser tratado adequadamente. Dever ser uma meta de educao permanente, dentro dos programas de melhoria de qualidade e meio ambiente, o entendimento dos operadores e supervisores das reas produtivas, quanto s razes e justificativas de se utilizar ou no as lagoas de emergncia. Diante desta perspectiva deve ficar claro para os operadores que um dia o efluente pode ser enviado com uma carga excessiva de poluentes para a ETE, devido ao fato das lagoas de emergncia encontrar-se com seu nvel baixo. Entretanto, em outros dias no pode ser mandado para a ETE nada alm do normal, devido s lagoas de emergncia encontrar-se cheias. 3.2. Quando se fala sobre a necessidade de controlar a carga de DBO5 existente no efluente na sada do tratamento biolgico e seu lanamento ao meio ambiente, entende-se que preciso limitar as cargas de poluentes e hidrulicas a um valor mximo que estipulado por um rgo ambiental do governo. O lanamento do efluente no ponto final de tratamento deve ser realizado com as menores cargas possveis. Com a exceo da implantao e aplicao de tratamentos do tipo tercirios, no possvel controlar as quantidades das cargas neste ponto final. A quantidade da carga poluente que sai da estao de tratamento sempre vai depender de trs fatores: da quantidade de cargas que entram na ETE, da relao destas cargas com o tamanho fsico da estao, e das condies operacionais em geral da ETE. Nos trabalhos efetivados e publicados no site nos meses anteriores, foram focalizadas algumas das variveis operacionais que necessitam ser bem controladas para que a eficincia da remoo da carga poluente possa ser mantida e que a carga de DBO5 efetivamente lanada seja controlada. Se ao longo da estao de tratamento no so controladas as variveis como: (1) a quantidade de oxignio dissolvido no tanque de aerao, (2) o pH do efluente, (3) a temperatura do efluente, (4) a quantidade de nutrientes disponvel, (5) a descarte do excesso de biomassa ou lodo gerado, entre outras, ento no ser possvel obter uma carga mnima de DBO5 no efluente final.CONCLUSESNeste trabalho foram tratados os assuntos referentes s cargas de DQO e DBO5 encontradas nos efluentes ao longo de uma estao de tratamento de uma fbrica de celulose moderna. Os itens tratados foram:1. Qual a faixa ideal de controle das cargas de DQO e DBO5 encontradas na entrada e na sada da fase de tratamento biolgico?2. Quais so os problemas e dificuldades no controle das cargas encontradas em um tanque de aerao?3. Como se podem controlar as cargas excessivas de DQO e DBO5?No prximo trabalho, parte 3, pretende-se abordar alguns detalhes do conceito de Relao de Alimentao com Massa (A/M ou F/M em ingls), onde as cargas de DQO e DBO5sero relacionadas com as concentraes de slidos nos tanques de aerao.

Foto de um tanque de aerao

2

OperacionalTabela N 1: Valores Tpicos para um Estao de Tratamento de Efluentes do Tipo de Aerao ProlongadoLocalDQODBO5VazoCarga DQOCarga DBO5mg/lmg/lm/diakg/diakg/dia[A] Efluente bruto sem slidos;2,01588333,59467,68029,677[B] Efluente bruto com slidos;1,48754756,18583,53630,728[A] + [B]89,779151,21660,406[D] Efluente bruto geral na entrada do tratamento biolgico;1,32869991,067120,93963,681[E] Efluente tratado lanado no meio ambiente.2943692,20327,0753,2781.2%Obs.: o valor atribudo ao erro da medidores

ProjetoTabela N 3: Valores de Projeto de uma Estao de Tratamento de Efluentes do Tipo de Aerao ProlongadoLocalDQODBO5VazoCarga DQOCarga DBO5mg/lmg/lm/diakg/diakg/dia[A] Efluente bruto sem slidos;1,95060771,856140,10043,600[B] Efluente bruto com slidos;79250566,14452,40033,400[A] + [B]138,000192,50077,000[D] Efluente bruto geral na entrada do tratamento biolgico;1,271526131,726167,47569,300[E] Efluente tratado lanado no meio ambiente.45632131,70660,0004,200

compartivoTabela N 2: Comparativo entre os Valores das Cargas de Projeto e Operacionais de uma Estao de Tratamento de Efluentes do Tipo de Aerao ProlongadaLocalVazo PROJETOVazo OPERACIONALCarga DQO PROJETOCarga DQO OPERACIONALCarga DBO5 PROJETOCarga DBO5 OPERACIONALm/diam/diakg/diakg/diakg/diakg/dia[A] Efluente bruto sem slidos;71,85633,594140,10067,68043,60029,677[B] Efluente bruto com slidos;66,14456,18552,40083,53633,40030,728[A] + [B]138,00089,779192,500151,21677,00060,406[D] Efluente bruto geral na entrada do tratamento biolgico;131,72691,067167,475120,93969,30063,681[E] Efluente tratado lanado no meio ambiente.131,70692,20360,00027,0754,2003,278

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PLANILHA DE ANALISES DA ETE - DADOS PARA ARCANJO79.29Efluente com fibras - Decantador primrioEfluente sem fibrasSada da Torre de ResfriamentoREATOR 1Reciclo de lodo 1REATOR 2Reciclo de lodo 2Decantadores SecundriosNutrienteLagoas de Emergncias e PluviaisVazoEfluente TratadoLodoCarga - Efluente EntradLagoas de Emergncias e PluviaisIPLinha de Fibras AcidoLinha de Fibras AlcalinoLavagem Linha de FibrasCOND BOMYASecagemDataProduo de Celulose TotalQ industrial (m/dia)pHVazo m/diaCondutividade (mS/cm)Cor (PtCo)SS entrada (mg/L)DBO Total entrada (mg/L)SST entrada (mg/L)DQO Total entrada (mg/L)pHSaidaSS sada (mg/L)SST sada (mg/L)DQO Soluvel sada (mg/L)pHVazo m/diaCondutividade (mS/cm)Cor (PtCo)DQO entrada (mg/L)SST (mg/L)DBO entrada (mg/L)pH - AntesCondutividadepH - PsTemperatura entrada torre (C)Temperatura sada torre (C)DQO entrada (mg/L)DQO entrada solvel (mg/L)DBO entrada (mg/L)Carga de DQO - kg/diaCarga DBO Kg/diaRedoxMaximo diaRedoxMinimo diaRedoxMedia dia diaRelao de DBO/DQON entrada (mg/L)P entrada (mg/L)SST 1 seletor (mg/L)SSV seletor 1 (mg/L)DQOSeletor 1(mg/L)SST Seletor 1A (mg/L)SSV seletor 1A (mg/L)DQOSeletor 1A(mg/L)SST reator (mg/L)SSV reator (mg/L)DQOReator(mg/L)SST/SSVDecantabilidadeIVLOD seletor (mgO2/L)OD Interm. (mgO2/L)OD sada (mgO2/L)Vazo, m/hSST (mg/L)SST seletor 2 (mg/L)SSV seletor 2 (mg/L)DQOSeletor 2(mg/L)SST seletor 2A (mg/L)SSV seletor 2A (mg/L)DQOSeletor 2A(mg/L)SST reator 2 (mg/L)SSV reator 2 (mg/L)DQOReator 2(mg/L)SST/SSVDecantabilidadeIVLOD seletor (mgO2/L)OD Interm. (mgO2/L)OD Sada (mgO2/L)Vazo, m/hSST (mg/L)Altura Manta 28 EscadaAltura Manta 28 CentroAltura Manta 28 ConeAltura Manta 29 EscadaAltura Manta 29 CentroAltura Manta 29ConeAltura Manta 30 EscadaAltura Manta 30 CentroAltura Manta 30 ConeNvel do tanque, %Vazo de Extrao LE, m/hLagoa 6 Nvel, %Lagoa 7 Nvel, %Lagoa 2Nvel, %Lagoa 4Nvel, %Lagoa 5Nvel, %Sulfeto Lagoa 6Sulfeto Lagoa 7m/diaCondutividade (mS/cm)pHTemperatura (C)Cor (PtCo)DQO sada (mg/L)DBO sada (mg/L)SST (mg/L)SS (mL/L.h)TurbidezN sada (mg/L)P sada (mg/L)Carga de DQO - Total Kg/diaCarga DBO Kg/diaRelao de DBO/DQO-Carga Eficincia (% DQO)Vazo de descarte de lodo (m/d)Entrada do adensador (%)Sada do adensador (%)Decanter 1 (%)Decanter 2 (%)Decanter 3 (%)Decanter 4 (%)Tonelada mida (ton/dia)Tot. Efluente Com Fibra m/diaTot. Efluente Sem Fibra m/diaTot. Efluente Pluvial m/diaTot. Efluente Lagoa Em. m/hTot. efluente tratado m/diaDQO Total Efluente EntradaDBO Total Efluente EntradaDBO/DQOCarga Efluente EntradaReciclo total de Lodo 1Reciclo total de Lodo 2Descarte de LodoArraste RIOkg de Lodo AterroTDHhorasPreciptao Tot DiammpH lagoa 06pH lagoa 07AGV Lagoa 06AGV Lagoa 07COND Lagoa 06COND Lagoa 07pHVazo m/diaCondutividade (mS/cm)SS (mg/L)DQO Soluvel (mg/L)SST (mg/L)PerdaFibras (mg/L)pHVazo m/diaCondutividade (mS/cm)DQO Total (mg/L)PerdaFibras (mg/L)pH Vazo m/diaCondutividadePerdaFibras (mg/L)Carga DQO SoluvelDQO solvel (mg/L)pH Vazo m/diaCondutividadeDQO Total (mg/L)Carga DQO Soluvel DQO solvel (mg/L)pH Vazo m/diaCondutividadeDQO Total (mg/L)DQO solvel (mg/L)pH Vazo m/diaCondutividadeDQO Total (mg/L)DQO solvel (mg/L)pH Vazo m/diaCondutividadePerdaFibras (mg/L)DQO Total (mg/L)DQO solvel (mg/L)PRODUCAO_TOTAL5081FYQ2001._DA.MV50-80-LAB-pHEflComFibETE5081FQ006.MV5081CdT005.MV50-80-LAB-CorEflcomFibETE50-80-LAB-SolSedEflComFibETE50-80-LAB-DBOEflComFibETE50-80-LAB-SolSuspEflComFibETE50-80-LAB-DQODecantEflComFibETE50-80-LAB-phDecPrimETE50-80-LAB-SolidSedimDecPrimETE50-80-LAB-SolidSuspDecPrimETE50-80-LAB-DQOSolDecPrimETE50-80-LAB-pHEflSemFibETE5081FQ014.MV5081CdT013.MV50-80-LAB-CorEflSemFibETE50-80-LAB-DQOTotEflSemFibETE50-80-LAB-SolSuspEflSemFibETE50-80-LAB-DBOEflsemFibETE5081pHC009.MV5081CdT011.MV5081pHT115.MV5081TT012.MV5081TT050.MV50-80-LAB-DQOTotTorreResfrETE50-80-LAB-DQOSolTorreResfrETE50-80-LAB-DBOTorreResfrETEClculoClculo5081AT120.MV5081AT120.MV5081AT120.MVClculo50-80-LAB-NitrogeniototalTorreResfrETE50-80-LAB-FosforoTotalTotTorreResfrETE50-80-LAB-SolSuspTotSelet1ETE50-80-LAB-SolSuspVolSelet1ETE50-80-LAB-DQOSelet1ETE50-80-LAB-SolSuspTotSelet1AETE50-80-LAB-SolSuspVolSelet1AETE50-80-LAB-DQOSelet1AETE50-80-LAB-SolSuspTotReat1ETE50-80-LAB-SolSuspVolReat1ETE50-80-LAB-DQOSolReat1ETEClculo50-80-LAB-Decantabilidade-Reator1-ETE50-80-LAB-IVLReat1ETE5081AT040A.MV5081AT040B.MV5081AT040C.MV5081FC108.MV50-80-LAB-SolSuspTotReciLodo1ETE50-80-LAB-SolSuspTotSelet2ETE50-80-LAB-SolSuspVolSelet2ETE50-80-LAB-DQOSelet2ETE50-80-LAB-SolSuspTotSelet2AETE50-80-LAB-SolSuspVolSelet2AETE50-80-LAB-DQOSelet2AETE50-80-LAB-SolSuspTotReat2ETE50-80-LAB-SolSuspVolReat2ETE50-80-LAB-DQOSolReat2ETEclculo50-80-LAB-Decantabilidade-Reator2-ETE50-80-LAB-IVLReat2ETE5081AT049A.MV5081AT049B.MV5081AT049C.MV5081FC109.MV50-80-LAB-SolSuspTotReciLodo2ETE50-80-LAB-NivelTqLodo1028 - Escada - ETE50-80-LAB-NivelTqLodo1028 - Centro - ETE50-80-LAB-NivelTqLodo1028- Cone - ETE50-80-LAB-NivelTqLodo1029 - Escada - ETE50-80-LAB-NivelTqLodo1029 - Centro - ETE50-80-LAB-NivelTqLodo1029- Cone - ETE50-80-LAB-NivelTqLodo1030 - Escada - ETE50-80-LAB-NivelTqLodo1030 - Centro - ETE50-80-LAB-NivelTqLodo1030- Cone - 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